Chemistry Unit 5-specific Reactions

Potassium manganate 1/2 equation

Ethanedioic acid half equation

Thiosulphate half equation

Iodine half equation

Bleach half equation

Forming copper (I) iodide solid equation

Oxidation of methanol

Dichromate breathalyser test

Combustion of benzene

Benzene + 3\(Br_2\) in the light goes to...

Name the meachnism

Benzene plus \(Br_2\) in the dark goes to...

And name the mechanism and any other reactants or conditions

How is a halogen carrier regenerated and from what?

Nitration of benzene reaction and conditions

What is the name and formula of the electrophile used in nitration of benzene?

How is a nitronium ion formed?

Sulfonation of benzene overall reaction, conditions and mechanism

What is fuming sulphuric acid?

What are 2 types of Friedel-craft's reactions?

Overall reaction for alkylation of benzene
and what is the mechanism?

Overall reaction for acylation of benzene
and mechanism?

What is the name of the electrophile in acylation of benzene?

By what mechanism is poly(phenylethene) produced?

What is the mechanism for benzene to cyclohexane and what catalyst is used?

Benzene + 3 \(H_2\) -->

And at what temperature?

Is phenol activating or deactivating?

Phenol + bromine water -->
Reaction, mechanism, conditions

What is observed when phenol is reacted with bromine water?

What is TCP and what is it used for?

How can you make TCP?

Phenol + (3) dil. nitric A

What reagent/s are used for nitration of phenol?

Benzene with potassium manganate does what?

What does \(NH_2\) do to benzene ring?

Describe a tetramethylamine ion

ethylamine + HCl

What type of salts do amines produce with HCl?

Amine + acid -->

How many phenylamines are there in a copper complex with water?

How many methyl amines are involved in a copper complex with water?

What is a stronger base, a primary alkyl amine or ammonia and why?

Which is a stronger base, phenyl amine or ammonia and why?

What is notable about the sulfonation of benzene?

Can phenyl amine form salts?
(give details)

Acyl chloride + amine

Chloromethane + methyl amine

Mechanism and products

Ethanoyl chloride + phenyl amine...

When phenol is nitrated what is the ratio of 2:4 nitrophenol?

4-aminophenol + ethanoic anhydride

And give the mechanism

Reduction of nitrobenzene overall reaction

Formation of nitrous acid

Amine + nitrous acid -->

Reaction and conditions

How would you convert an amine into an alcohol?

Phenyl amine + nitrous acid

T > 5\(\omicron\)

Phenyl amine + nitrous acid + HCl

T < 5\(\omicron\)

Can you form benzenediazonium ions from aliphatic amines?

Can you form benzenediazonium ions from aromatic amines?

How do you form a benzenediazonium ion?
And what by product is produced?

Between what 2 things does a coupling reaction happen?

Conditions for coupling reaction

benzenediazonium chloride + phenol

Where is the positive charge on a benzenediazonium ion?

How many bonds are there between the N's of a benzenediazonium chloride?

How many bonds are there between the N's of an azo dye?

Acyl chloride + ammonia

Polyesters are formed by what type of polymerisation?

Polyamides are formed by what type of polymerisation?

Polypeptides are formed by what type of polymerisation?

What type of polymer is PET?

What type of polymer is Nylon?

What type of polymer is Kevlar?

Poly(propenamide) is formed by which type of reaction?

Poly(ethenol) is formed by which type of reaction?

Ninhydrin + amino acid -->

How is Ruheman's purple pigment produced?

Is phenol solution acidic or alkaline?

Phenol + oxidising agent

How would you add a carbon to a chain?

How would you add a carbon to aromatic molecules?

Hofmann's degradation reaction

Hofmann's degradation conditions

Hunsdieker reaction

Conditions of Hunsdieker reaction