Unit 2 Module 3

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aphillips
Flashcards by aphillips, updated more than 1 year ago
aphillips
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Enthalpy heat content that is stored in a chemical system
Exothermic enthalpy of the products is smaller than the enthalpy of the reactants resulting in heat loss to the surroundings Enthalpy change = -ve
Endothermic enthalpy of the products is greater than the enthalpy of the reactants, resulting in heat being taken in from the surroundings Enthalpy change = +ve
Activation Energy minimum energy required to start a reaction by the breaking of bonds
Standard State physical state of a substance under standard conditions
Standard enthalpy change of reaction enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation under standard conditions, all reactants and products in their standard states
Standard enthalpy change of combustion enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions, all reactants and products being in their standard states
Standard enthalpy change of formation enthalpy change that takes place when one mole of a compound is formed from its constituent elements in their standard conditions enthalpy of formation of an element = 0kJ/mol
Specific heat capacity energy required to raise the temperature of 1g of a substance by 1degC
Bond enthalpy enthalpy change that takes place when breaking 1 mole of a given bond in the molecule of a gaseous species by homolytic fission
Average bond enthalpy average enthalpy change that takes place when breaking 1 mol of a given type of bond in the molecules of a gaseous species by homolytic fission
Hess' Law if a reaction can take place by more than one route and the initial and final conditions are the same, the total enthalpy change is the same for each route
rate of reaction change in concentration of a reactant or product in a given time
Homogeneous catalyst catalyst has a different physical state from the reactants
Heterogeneous catalyst catalyst and reactants are in different physical states
Boltzmann distribution distribution of energies of molecules at a particular temperature - usually shown as a graph
Dynamic equilibrium equilibrium that exists in a closed system when the rate of the forward reaction is equal to the rate of the reverse reaction
Le Chatelier's principle when a system in dynamic equilibrium is subjected to a change, the position of equilibrium will shift to minimise the change
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