Chapter 16 Organic Synthesis

Description

AS level Chemistry Flashcards on Chapter 16 Organic Synthesis , created by Hannah Smith on 16/04/2017.
Hannah Smith
Flashcards by Hannah Smith , updated more than 1 year ago
Hannah Smith
Created by Hannah Smith almost 7 years ago
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Resource summary

Question Answer
Alkane to haloalkane Radical Eubstitution X2, UV light,
Haloalkane to Primary Alcohol Nucleophilic Substitution NaOH, reflux
Primary Alcohol to Aldehyde Oxidation Distillation, acidified K2Cr2O7 (dichromate), H2SO4
Primary Alcohol to Ester Esterification Conc. H2SO4, heat, methanoic acid.
Naming Esters e.g. ethly (for no. carbons not in group) methanoate (from carboxylic acid used, methanoic acid) ethyl methanoate
Primary Alcohol to Alkene Elimination (H2O comes off) Conc. H2SO4, heat
Primary Alcohol to Haloalkane Nuclophilic Substitution NaX, conc. H2SO4 (acid catalyst
Aldehyde to Carboxylic Acid Oxidation reflux, acidified K2Cr2O7, H2SO4
Alkene to Primary Alcohol Electrophilic Addition/ Hydration H2O as steam, conc. H2PO4, 300C
Alkene to Haloalkane Electrophilic Addition HX, room temperature, (aqueous, I think)
Alkene to Alkane Hydrogenation H2 gas, Nickel catalyst, 150C
Alkene to Secondary Alcohol Electrophilic Addition/Hydration Conc. H2PO4, H2O as steam
Secondary Alcohol to Alkene Elimination of H2O Acid catalyst, heat or conc. H2SO4,
Secondary Alcohol to Ketone Oxidation Reflux, acidified K2Cr2O7, HrSO4
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