Is defined as a d-block
element that forms at
least one ion with a
partially filled d-subshell
Fe [Ar]3d⁶4s²
Fe²⁺3d⁶4s⁰
Fe³⁺3d⁵4s⁰
Electrons get
lost from the 4s
orbital before
the 3d.
Chromium and Copper
display different
arrangements as they feel
more stable because of the
half filled and full filled d-sub
shell.
Cr [Ar]3d⁵4s¹
Cu [Ar]3d¹⁰4s¹
Chemical Properties
of Transition Metals
Variable oxidation
states
Due to the difference between
succesive ionisations in the 3d
and 4s sub shells, therefore
multiple electron loss is
possible.
Coloured ions
When the unpaired electron is in
the 3d sub shell absorbes visible
light the unpaired electron gets
excited. As Transition metals are
surrounded by ligands the d orbital
splits up into two energy levels
Complexes
Transition metals are able to
form complexes because their
3d orbital can accomodate the
electron donated by the ligand.
Catalytic Activity
Metals can act as heterogeneous catalysts,
providing a surface onto which gaseous
reactants can be adsorbed. They can also
act as homogeneous catalysts due to their
different oxidation states.