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5939642
(BONDING AND CALCULATIONS, 2a) 1
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Chemistry 2a
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Eleanor Rose
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Eleanor Rose
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(BONDING AND CALCULATIONS, 2a) 1
Atoms, compounds and isotopes
mass number: total number of protons and neutrons
number of neutrons; mass number minus atomic number
atomic number: number of protons
proton: mass 1, charge +1
neutron: mass 1, charge 0
electron: mass 1/2000, charge -1
compounds are chemically bonded
compounds are formed when atoms of 2 or more elements are chemically combined together
isotopes are the same except for an extra electron
isotopes are different atomic forms of the same element, which have the SAME no. of PROTONS but DIFFERENT no. of NEUTRONS
isotopes e.g. C12 = 6 neutrons and C14 = 8 neutrons but both have 6 protons & 6 electrons
Ionic bonding
ionic bonding = transferring electrons
a shell with one electron wants to get rid of it
a shell with 7 electrons wants to get one extra electron
very strong electrostatic forces of attraction between oppositely charged ions, in all directions
atoms lose or gain electrons to form charged particles (called ions)
ionic compounds all have similar properties
high melting points and high boiling points - due to strong attraction between ions
dissolves easily
ionic compounds have a regular lattice stucture
they always have giant ionic lattices
the ions form a closely packed regular lattice arrangement
ions have the electronic structure of a noble gas
charge on the positive ions is the same as the group number of the element
overall charge of any compound is zero
sodium chloride = NaCl
magnesium chloride = NgCl 2
covalent bonding
= sharing electrons
only share electrons in their outer shells (highest energy levels)
both atoms want a full outer shell
having a full outer shell gives them the electronic structure of a noble gas
simple molecular substances
forces of attraction between these molecules are very weak
melting/boiling points = very low
molecules are easily parted from each other
don't conduct electricity
giant covalent structures are macromolecules
no charged ions
all the atoms are bonded to each other by strong covalent bonds
very high melting/boiling points
don't conduct electricity
main examples are diamond and graphite
metallic structures
metal properties are all due to the sea of free electrons
good conductors of heat/electricity
electrons are free to move
regular structure, strong forces of electrostatic attraction between the +ve metal ions and the -ve electrons
allow layers of atoms to slide over each other - metals can be bent/shaped
new materials
smart materials - e.g. shape memory alloy
when it's cool, you can bend it
if heated above certain temp. it goes back to 'remembered shape'
Nitinol is also used for dental braces - warms in mouth and tries to return to a 'remembered shaoe', gently pulling teeth with
nanoparticles (nanoscience)
high surface area to volume ratio
new cosmetics e.g. sun tan cream/deodorant made using nanoparticles
polymers
nanotubes conduct electricity
forces between molecules determine properties of plastics
weak; held together by weak intermolecular forces/free to slide over each other
strong; stronger intermolecular forces between polymer chains (crosslinks) that hold the chains firmly together
thermosoftening; forces between chains = easy to overcome...easy to melt plastic. When cooled, hardens into new shape
thermosetting; have crosslinks...solid structure, doesn't soften when it's heated, stong, hard, rigid
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