The Kinetic Particle Model

Beschreibung

The kinetic particle model describes matter as consisting of particles in constant motion, except at absolute zero
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Kinetic particle model - Matter consists of small particles - They are in constant rapid motion or vibration - Average velocity of particles (kinetic energy) is proportional to the temperature of the substance
Particle movement - Kinetic energy is due to movement - Particle movement increases = greater kinetic energy - E.g. translational (straight lines), rotational (rotates about centre of mass), vibrational (moves towards/away from centre of mass)
Particle position - Potential energy is due to particles’ positions - Distance between particles increases = greater potential energy - PE in gases > PE in liquids > PE in solids - To increase PE, energy must be supplied to overcome intermolecular forces (so particles can move more freely)
Solid state - Molecule arranged in regular pattern (lattice) - Vibrate backwards/forwards but are held in positions by attractive forces and cannot move around
Melting - At melting point, vibrations are so violent that lattice breaks down - Heat is absorbed without change in temperature (heat is used to free molecules from lattice forces) - Molecules gain potential energy and are free to move around (becomes liquid)
Liquid state - Molecules same distance apart but free to move around - liquid can pour and adopt shape of container - Still a force of attraction, so liquid has definite surface
Boiling - At boiling point, molecules leave liquid and become gas - Temperature is steady (heat is used to free molecules from forces of attraction)
Gasesous state - Molecules much further apart and move faster - Almost no force of attraction - Move out to fill container; pressure is caused by force of molecules hitting container walls
Absolute zero - ‘Lowest possible temperature’ is -273ºC - So much heat is removed that particles stop moving (no kinetic energy) - Kelvin scale (K) is also called absolute scale of temperature as it starts at absolute zero - Celsius to Kelvin: + 273ºC
Temperature - Measure of the average kinetic energy of particles in a substance - Determines direction of heat flow
Thermometer - Relies on change in physical property of a material used in the thermometer as temperature changes - E.g. regular expansion of a liquid (mercury or alcohol)
Kinetic energy The energy a body possesses due to its motion
Thermal equilibrium - Occurs when two isolated systems at different temperatures come into contact and final temperature is same for both systems - At thermal equilibrium there is no net transfer of energy from system to system
Law of conservation of energy Energy can be neither created nor destroyed. It can change forms and flow from one place to another
Internal energy (aka thermal energy) - Sum of KE and PE of particles in a system - Impossible to measure (can only measure change in energy) - Different phases of same substance at same temperature contain different amounts of internal energy e.g. 1 g of liquid water at 0ºC contains more internal energy than 1 g of ice at 0ºC
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