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GCSE Science (Chemistry) Note on Group 7 - Halogens, created by eibhlinjones200 on 01/06/2013.

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Group 7 elements are known as 'Halogens'
  • Group 7 is made up of fluorine, chlorine, bromine, iodine and astatine
  • All Group 7 elements have 7 electrons in their outer shell so they all react by gaining one electron to form a negative ion.
  • This means they all have similar properties.
  • As you go down group 7 the melting points and boiling points of the halogens increase.
  • This means at room temperature:                
As you go down group 7, the halogens become less reactive - there's less inclination to gain the extra electron to fill the outer shell when it's further out from the nucleus (there's a larger atomic radius).
  • Chlorine (Cl2) is a fairly reactive, poisonous, dense green gas (low boiling point)
  • Bromine (Br2) is a dense, poisonous, orange liquid
  • Iodine (I2) is a dark grey crystalline solid (high boiling point)
Reduction is the gain of electrons:-
  • Halogens are keen to gain an electron to form 1- ion with a stable electronice structure.
  • The more reactive the halogen the happier it is to gain an electron.
  • Gain of electrons is called reduction
The Halogens react vigorously with alkali metals (group 1 elements) to form salts called 'metal halides'. 

sodium + chlorine → sodium chloride

2Na(s) + Cl2(g) → 2NaCl(s)
More reactive halogens will displace less reactive ones:-
Chlorine can displace bromine and iodine from a solution of bromide or iodide. Bromine will also displace iodine. You could be asked to predict the results of displacement reactions using other halogens - just remember, more reactive halogens displace less reactive ones.
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