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306685
Enzyme Catalysis
Descripción
Topic 3 - Metabolism Mapa Mental sobre Enzyme Catalysis, creado por kathrynmoar el 27/10/2013.
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topic 3 - metabolism
topic 3 - metabolism
Mapa Mental por
kathrynmoar
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kathrynmoar
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Resumen del Recurso
Enzyme Catalysis
Reactions that have a negative net free energy change may occur in the cell.
Those that have a positive or zero free energy cannot occur
Enzymes do not affect the equilibrium position of a reaction
Chains are folded to form pockets or clefts that constitute where the reaction occurs
several weak bonds are needed.
Nature
First stage
substrate is converted to a transition state
readily converted into a product in second stage
Reaction can occur if there is a decrease in free energy in going from starting material to product
Energy profile involves passing over an "energy hump" where the transition state is at higher free energy than the starting materials.
energy is required to reach the transition state
reaction rate is determined by the rate of formation of the transition state
antibodies produced against the transition state. They are called "abzymes"
interaction between the substrate and enzyme so that the enzyme changes shape slightly.
this is known as the "induced fit" mechanism.
hexokinase consists of two wings that fold around glucose as it binds to the enzyme
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