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Equilibrium Constant - Part II

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  1. 1Kc/ Equilibrium constantA measure of the position of the equilibrium; the magnitude of an equilibrium constant indicates whether there are more reactants or more products an equilibrium system.
  2. 2Homogeneous EquilibriumAn equilibrium in which all the species are making up the reactants and products have the same physical state.
  3. 3Heterogeneous EquilibriumAn equilibrium in which the species making up the reactants and products have different physical states.
  4. 4EquilibriumThe rate of the forwards reaction is equal to the reverse.
  5. 5KpUsed for gaseous equilibria. It doesn't use concentrations, instead requires partial pressures.
  6. 6Partial PressureIt is the contribution each gas makes towards the total pressure. = mole fraction x total pressure.
  7. 7What doesn't affect K?Concentration, pressure and catalysts don't affect K as they are quantities.
  8. 8What affects K?Temperature does as its a condition.
  9. 9Exothermic (increasing temperature)Favours endothermic direction
    Shifts to the left
    Kp decreases
  10. 10Exothermic (decreasing temperature)Favours exothermic direction
    Shifts to the right
    Kp increases
  11. 11Endothermic (increasing temperature)Favours the endothermic direction
    Shifts to the right
    Kp increases
  12. 12Endothermic (decreasing temperature)Favours the exothermic direction
    Shifts to the left
    Kp decreases
  13. 13Changing [B] / [A]Disables the equilibrium because K is a constant value and the expression is now higher/lower than k. [B] or [A] must increase or decrease until the expression is equal to k. When they are equal to k, equilibrium is restored.
  14. 14Temperature (K)Quantities [B] / [A] don't change. Equilibrium is affected by temperature. K must change to a new value. This will disable the equilibrium as the values don't match k. So the quantities must adjust.

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El usuario ha eliminado su información de asignaturas Fichas sobre Equilibrium Constant - Part II, creado por Usuario eliminado el 23/09/2017.
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Usuario eliminado · sep 2017
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23 sep 2017
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  • Creado por Chloe Drewery · 10 sep 2017
  • Copiado por Chloe Drewery · 23 sep 2017
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