Orgo 2 Exam 2

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umich orgo 2 exam 2
Katherine Siller
Flashcards by Katherine Siller, updated more than 1 year ago
Katherine Siller
Created by Katherine Siller about 6 years ago
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Resource summary

Question Answer
carboxylic acid + SOCl2 or PCl3
carboxylic acid + carboxylic acid
carboxylic acid + H2SO4, CH3OH
acyl transfer: anionic nuc 2 steps tetrahedral intermediate
acyl transfer: neutral nuc + weak base 3 steps zwitterion tetrahedral intermediate
acyl transfer: neutral nuc + strong acid 6 steps tetrahedral intermediate
primary alcohol + CrO3 + H2SO4 + H2O
aldehyde + CrO3 + H2SO4 + H2
+ H2SO4 + H2O
+ NaOH + H2O
Ph-MgBr + CO2 + H3O(+)
+ TsOH -----> CH3OH + H2O
+ TsOH
+ LiAlH4 aldehyde, then won't stop (can be protonated to primary alcohol)
carboxylic acid won't reaction with NaBH4 only LiAlH4
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