Alcohol

Description

NCEA Level 3 Chemistry (3.5 Organic Compounds) Mind Map on Alcohol, created by Lauren Collins on 08/31/2015.
Lauren Collins
Mind Map by Lauren Collins, updated more than 1 year ago
Lauren Collins
Created by Lauren Collins over 9 years ago
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Resource summary

Alcohol
  1. (Secondary alcohol) Acidifed dichromate - orange to green (oxidised)
    1. Ketone
      1. Ketone cannot be further oxidised
    2. (Primary alcohol) Acidified dichromate/permanganate and heat (oxidised)
      1. Aldehyde
        1. Tollen's Reagent. Observations: A fine black precipitate or a silver mirror
          1. Benedicts or Fehlings solutions. Observations: blue solution to a red-brown precipitate
            1. Acidified dichromate or permanganate, heat
              1. Carboxylic Acid
                1. R-OH, conc. H2SO4, heat (condensation)
                  1. Ester
          2. PCl5, PCl3, SOCl2, conc. HBr acid. Also Lucas Reagant (goes cloudy: Tertiary = fast, Secondary = slow w/ heat, Primary = no reaction. (substitution)
            1. Haloalkane
              1. NH3, heat
                1. Amine
                2. OH-, heat
              2. conc. H2SO4, heat
                1. Alkene
                  1. Pt Catalyst
                    1. Alkane
                      1. KOH(alc), heat
                        1. Halogen, light
                      2. Halogen or hydrogen halide
                    2. Tertiary alcohols are not oxidised
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