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Functional Groups

Classification of Smells:

  • Putrid- repulsive, gross
  • Camphor- pungent, medicinal
  • Sweet- flowery or fruity 🏳️‍🌈
  • Minty- green herbal smell
  • Fishy- very distinctive, like seafood

Organic Molecules contain a carbon backbone and one or more functional group

  • Hydrocarbon- backbone for functional groups. They include:
    • Alkanes- only single bonds
    • Alkenes- contains double bonds
    • Alkynes- contains triple bonds
  • Functional group- a group of atoms bonded together in a specific way
    • define the chemical and physical properties of a compound

Types of Functional Groups:

  • Alcohol
    • Functional group: -OH
    • Smell: Camphor/Medicinal
    • Compound names end in: -ol
  • Amine
    • ​​​​​​​​​​​Functional group: -N
    • Smell: Fishy
    • Compound names end in: -amine
  • Carboxylic Acid​​​​​​​
    • ​​​​​​​​​​​Functional group: -COOH
    • Smell: Putrid
    • Compound names end in: -ic acid
  • Ketone
    • ​​​​​​​​​​​Functional group: -COOC
    • Smell: Sweet
    • Compound names end in: -one​​​​​​​
  • Amino Acids
    • ​​​​​​​Contain two functional groups- amine and carboxylic acids
    • Building blocks of protein
    • "R" group: represents a sidechain

Electron Domains

The VSEPR (Valence Shell Electron Pair Repulsion) Theory states that molecules will attain whatever shape keeps the valence electrons of the central atom as far apart from one another as possible.

  • Unshared pairs of electrons on the central atom determine the shape.
  • Electron pairs REPEL each other.

 

  • Electron domain: The space occupied by valence electrons in a molecule, either a bonded pair(s) or a lone pair. Electron domains affect the overall shape of a molecule.
  • Electron domain theory: The idea that every electron domain in a molecule is as far as possible from every other electron domain in that molecule.
    • 4 bonding pairs, 0 lone pairs- tetrahedral shape (109.5 degrees)
    • 3 bonding pairs, 1 lone pair- trigonal pyramidal (105 degrees)
    • 2 bonding pairs, 2 lone pairs- bent
    • 2 bonding pairs (double bonds), 0 lone pairs- linear (180 degrees)
      • Lone pairs occupy more space than bonding electron pairs.

      • Double bonds occupy more space than single bonds.