Starch cellulose & chitin

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What is the difference between the structure of glucose isomers a-glucose and b-glucose?
What is a polymer? A large molecule formed in polymerisation of monomers. Joined by condensation and broken by hydrolyses.
Name the main 5 macromolecules. Protein Starch Cellulose Glycogen DNA
Name and explain the properties of macromolecules. Their so big their insoluble which is important for them to carry out their function. Their osmotically inactive and so can be stored in cells without osmotic effect.
What are glucose & starch a polymer of? What is cellulose a polymer of? What is protein a polymer of? a-glucose b-glucose amino acids
What is starch used for? To store polysaccharides.
What are the elements that make starch? What is the structure of each of these? Amylose and amylopectin, both polymers of a-glucose. Amylopectin - long linear molecule wound into a helix making it easy for glucose to be removed. Amylose - helical structure.
Describe the branch structure of amylopectin and its properties? The branches make it easier to break down, glucose can then be released quicker.
How does the structure of amylose allow the starch & iodine reaction? What is the result of this interaction? Amylose has a helical structure. Rows of iodine sit inside amylose helix interacting, this changes the light absorbing properties and it appears blue. Different amylose gives different shades of blue.
What are the 4 structural carbohydrates? Starch Glycogen Cellulose Chitin
What is starch used for? Why is it so important? It's a plant storage carbohydrate, so stores glucose in plants. If glucose wasn't stored as starch it would create a negative water potential in cells drawing water by osmosis. Starch is insoluble and has branches so brakes down quickly.
What is glycogen used for? Whys is it important? Glycogen stored glucose in animals. Like amylopectin it's a-glucose molecules have both 1-4 & 1-6 glycosidic so is highly branched and quick to release glucose. Energy for metabolic processes.
What is the structure of cellulose? Polymer of b-glucose joined by glycosidic bonds in long straight lines. Each b-glucose molecule is rotated 180' from previous allowing hydrogen bonds between OH groups of adjacent chains.
What are the uses of cellulose? Cellulose chains form microfibril, many microfibril form a cellulose fibre, Cellulose fibre then forms a cell wall. It's joined by many hydrogen bonds giving it a strong structure.
What is the structure of chitin? What are the uses? Made of chains of b-glucose monomers rotated 180' from previous. Hydrogen bonds between chains form microfibrils. Some OH groups have b-glucose monomers are replaced by nitrogen. Chitin is strong and lightweight for insect exoskeleton.
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