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Benedict's or Tollens' Reagents: Reducing Sugars

Danielle Thibeadeaux Organic Chemistry Inglés 7 fichas

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  1. 1Benedict's reagent an ______ solution containing a _____ _____ complex ion.Benedict's reagent an alkaline solution containing a cupric citrate complex ion.
  2. 2Tollens' solution _________ oxidize giving a positive test with _____ and _____.Tollens' solution [Ag+(NH3)2OH-] oxidize giving a positive test with aldoses and ketoses.
  3. 3The tests are ________ even though aldoses and ketoses exist primarily as _____ ________.The test are positive even though aldoses and ketoses exist primarily as cyclic hemiacetals.
  4. 4Benedict's solution is the color ______ from the _____. Once it oxidizes an aldose or ketose it becomes a ______ color of the precipitate ______.Benedict's solution is the color blue from the Cu+2. Once it oxidizes an aldose or ketose it becomes a brick-red color of the precipitate CU2O.
  5. 5In alkaline solution ketoses are converted to _______ which are then oxidized by the ________ complexes.In alkaline solution ketoses are converted to aldoses which are then oxidized by the cupric complexes.
  6. 6Sugars that give a positive test with ________ or ________ solutions are known as ________.Sugars that give a positive test with Tollens' or Benedict's solutions are known as reducing sugars.
  7. 7All __________ that contain a ________ ______ give positive test.All carbohydrates that contain a hemiacetal group give positive test.

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