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Chap.4: Fundamentals of Material Balances

Amirah Hill Principles of Chemical Engineering University Inglés 3,0Valoración media 3,0 de 5 (1 valoración) 34 fichas

Chap.4: Fundamentals of Material Balances

Fichas del conjunto (34)

  1. 1Batch ProcessThe feed (charge) enters the tank all at once. Once the reaction is complete, the product is removed all at once.
  2. 2Continuous processfeed is always flowing in with a high amount of reactant and effluent is always coming out with a high concentration of product. (Product is constantly withdrawn from the rxtr)
  3. 3Semi-batch processNot continuous nor batch
    ex. One reactant is added to a vessel and then later, another one is slowly added.
  4. 4Steady-StateA continuous process where process variables like:
    -flow rate
    -temperature
    -pressure, etc...
    operate at nominally (by name) consistent values
  5. 5Transient (Unsteady-state)A process with changing process variables. By nature, semi-batch and batch processes are transient while continuous processes could be either or.
  6. 6General Balance equationInput - Output + Generation - Consumption = Accumulation
  7. 7Gen. Balance Eqn for Non-reactive systemThere's no generation or consumption in a non-reactive system so:
    Input - Output = Accumulation
  8. 8General Balance eqn for reactive processesGeneration and Consumption depend on the balance at hand.
    If balance is on a total mass or atomic species, there is no generation or consumption since mass is neither created nor destroyed.
  9. 9FlowchartUsing boxes and other symbols to represent process units and lined with arrows to represent input and output.
  10. 10ScalingMasses and NOT mass fractions of all streams can be multiplied by a common factor and the process would remain balanced.
    *scaling up/ scaling down
  11. 11Basis of CalculationAn amount (in either mass or moles) of flow rate of one stream or stream component in a process. Usually use 1 or 100.
  12. 12Degrees of FreedomDOF<0 underspecified and not solvable
    DOF=0 solution is possible
    DOF>0 overspecified and not solvable
  13. 13DOF for non-reactive process+unknowns
    -material balances (species)
    -relationships
    *For multiple units, ensquare each subsystem and do a DOF analysis
  14. 14RaffinateThe phase rich in the diluent (water for example)
  15. 15ExtractPhase rich in the solvent.
  16. 16Stoichiometric ProportionThe ratio of two reactants A and B in a balanced eqn.
  17. 17Limiting reactantA reactant is limiting is it is present in less than its stoichiometric proportion relative to every other reactant.
  18. 18Fractional ExcessFor percentage excess, multiply by 100.Fractional Excess
  19. 19Fractional ConversionFractional Conversion
  20. 20YieldYield
  21. 21SelectivitySelectivity
  22. 22DOF for Reactive Molecular species balance+No. unknown labeled variables
    +No. independent chem reactions (cannot mult./add one eqn to get the other)
    -No. independent molecular species
    -No.relationships
  23. 23DOF for Atomic species balance+No. identified/labeled unknowns
    - No. independent atomic species
    -No. non-reactive species
    -No. other relationships
  24. 24DOF for extent of reaction+No. labeled unknowns
    +No. independent chemical rxns
    -No. independent reactive species
    -No.independent non-reactive species
    -No. other relationships
  25. 25CombustionRxn of a fuel with oxygen to produce CO2 and H2O
  26. 26Partial/Incomplete CombustionA combustion reaction where CO is formed from a hydrocarbon.
  27. 27Composition on a Wet BasisComponent moles fractions of a gas that contains water.
  28. 28Composition on a dry basisThe component mole fractions of a gas without water.
  29. 29Stack gas / Flue gasProduct gas that leaves a combustion furnace
  30. 30Theoretical OxygenAmount of oxygen produced based on the balanced equation
  31. 31Percent excess airTrick: If 50% excess, then 1.5 (moles air)theoPercent excess air
  32. 32Excess airThe amount of air fed to the reactor that exceeds the theoretical air.
  33. 33Molecular Weight ( MW ) of air29.00 (kg air/kmol, lbm air/lb-mole, etc...)
  34. 34Composition of Air0.21 mol O2/mol air
    0.79 mol N2/mol air

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From Felder and Rousseau
Creado por
Amirah Hill
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Valoración
Valoración media 3,0 de 5 (1 valoración)

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