Chem Flashcards

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A-Levels Chemistry Flashcards on Chem Flashcards, created by jacksearle on 04/06/2013.
jacksearle
Flashcards by jacksearle, updated more than 1 year ago
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Created by jacksearle almost 11 years ago
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Resource summary

Question Answer
Structural Isomers Molecules with the same molecular formula but with different structural Formula
Stereo Isomers Compounds with same structural formula but different arrangement in space
When can E/Z isomerism occur - Restricted rotation around C=C bond -When each Carbon atom on C=C bond has 2 different groups of atoms bonded to it
E/Z Isomers E - Opposite Z- together
Homolytic Fission Breaking of a covalent bond with one of the bonded electrons going to each bonded atom to form 2 radicals
Heterolytic Fission Breaking of a covalent bond with bond bonded electrons going to one of the bonded atoms to form to ions
Electrophile Electron Pair Acceptor
Nucleophile Electron Pair Donator
Radical Species with an unpaired electron
Percentage yield Actual Amount/Predicted amount x100
Atom Economy Sum of Mr of desired products/Sum of Mr of all products x100
Hydrocarbon An organic compound consisting of Hydrogen and Carbon only
Alkane Saturated Hydrocarbon homologous series with General Formula Cn H2n+2
Saturated C-C single bonds only
Fractional Distillation Separation of components in a liquid mixture into fractions which differ in boiling point by means of distillation
Catalytic Cracking The breaking down of a long chain alkane to form a new alkene and a new alkane which are more useful products
Complete combustion reacts completely with oxygen under standard conditions to form CO2 And H2O
Incomplete Combustion When a compound reacts incompletely with oxygen to form CO and H2O
Non-Renewable Used up quicker than it's made
Biodiesel A fuel made up of completely renewable plant based material
Initiation First step in radical substitution, breaking of a bond via homolytic fission that creates 2 radicals
Propagation Two steps were Radicals are used up and then re-generated
Termination Two radicals join together to make one product
Alkenes Homologous series with general formula Cn H2n
Unsaturated contains C=C double bonds
Pi Bond Formed from sideways overlap of p-orbitals
Addition reaction A reactant is added to an unsaturated molecule to form a saturated molecule
Polymer Long molecular chain built from small monomer units
Monomer A small molecule that combines with many other monomers to form a polymer
Biodegradable Material that is broken down naturally in the environment by living organisms
Non biodegradable Not broken down naturally
Volatility The ease with which a liquid turns into a gas
Esterification alcohol + carboxylic acid --> ester + water
Elimination The removal of a molecule from a saturated molecule to make an unsaturated molecule
Elimination The removal of a molecule from a saturated molecule to make an unsaturated molecule
Hydrolysis A reaction with water or Aqueous Hydroxide ions that breaks a compound down into two compounds
Exothermic More energy given out during bond making than is taken in during bond breaking
Endothermic More energy is taken in during bond breaking than is given out during bond making
Activation Energy Minimum energy required to start a reaction via the breaking of bonds
Standard Conditions 100kPa 298K conc of 1moldm-3
Enthalpy change of a reaction The enthalpy change that accompanies a reaction in the molar quantities shown in the chemical equation under standard conditions etc
enthalpy change of formation enthalpy change when one mole of a compound is formed from it's constituent elements in their standard states under standard conditions
Enthalpy change of combustion Enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions, all reactants/products in standard states
Average bond enthalpy Average enthalpy change that takes place when breaking by homolytic fission one mole of a given type of bond in the molecules of a gaseous species
Hess' law If a reaction can take place by more than one route, then the enthalpy change is the same for all routes
Catalyst Substance that speeds up rate without being used up
Dynamic Equilibrium Equilibrium in a closed system when rate of forward=rate of reverse
Le Chatelier's when a reaction in dynamic equilibrium is subjected to a change, the equilibrium will shift to minimise that change
Greenhouse Effect Process in which the absorption and emission of IR radiation by atmospheric gases warms the planet
Greenhouse Gases CO2 H2O METHANE
Empirical Formula The simplest whole number ratio of atoms of each element present in a compound
Molecular Formula The number of atoms of each element in a molecule
General Formula Simplest algebraic formula of a member of a homologous series
Structural Formula Formula showing the minimal detail for arrangement of atoms in a molecule
Skeletal Formula Simplified organic formula, Hydrogen atoms removed from alkyl chains, leaving just a carbon skeleton with associated functional groups
Homologous series A series of organic compounds with the same functional group but with each but with each successive member differing by CH2
Functional Group A group of atoms responsible for a compounds chemical reactions
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