Challoner 2021: EdExcel GCSE Chemistry Paper 2 (Specific Topics)

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GCSE Chemistry Flashcards on Challoner 2021: EdExcel GCSE Chemistry Paper 2 (Specific Topics) , created by Malachy Moran-Tun on 18/05/2021.
Malachy Moran-Tun
Flashcards by Malachy Moran-Tun, updated more than 1 year ago
Malachy Moran-Tun
Created by Malachy Moran-Tun almost 3 years ago
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Question Answer
What is Ionic Bonding? Transfer of Electrons Between a Metal and a Non-Metal
Why are Ionic Bonds Strongly Attracted to Each-other? The Electrostatic Forces of Attraction hold the Ions Together
What are Group 1 Elements also known as? Alkali Metals
How many Outer Electrons do Group 1 Metals have? One outer electron
What Physical Properties do Group 1 Metals have? > Low melting and boiling points (compared with other metals) > Very soft - can be cut with a knife
Why do Group 1 Metals NOT form Covalent Bonds? > Form ionic compounds > Loose the outer electron very easily > Outer electron CANNOT be shared
Why are Group 1 Metals So Reactive? > Easy to loose the outer electron > Loosing the outer electron forms a stable electronic structure (1⁺ ion)
How and Why does Reactivity Change as you do Down Group 1? > Reactivity increases > Outer electron is more easily lost > Electron is further from the nucleus > Electrostatic shielding from shells > Less attraction to the nucleus > Less energy required to remove electron
What is the General Word Equation for Reactions with Water and Alkali Metals? Alkali Metal + Water → Alkali Metal Hydroxide + Hydrogen
Why do Alkali Metals from Alkali in Water? They produce hydroxides which contain OH⁻ ions
What happens when Lithium Reacts with Water? > Bubbles Fiercely on Water Surface > 2Li(s) + 2H₂O(l) → 2LiOH(aq) + H₂(g)
What happens when Sodium Reacts with Water? > Melts into a ball and fizzes as it moves around on the surface > 2Na(s) + 2H₂O(l) → 2NaOH(aq) + H₂(g)
What happens when Potassium Reacts with Water? > Reacts very rapidly and bursts into a lilac flame as it flies about the surface > 2K(s) + 2H₂O(l) → 2KOH(aq) + H₂(g)
What are Group 7 Elements also known as? Halogens
How many Outer Electrons do Group 7 Elements have? Seven outer electrons
What type of Molecule do Halogens (Naturally) Exist as? Diatomic Molecules (e.g. Cl₂, Br₂, I₂ etc.)
Why do Halogens Exist as Diatomic Molecules? Share one pair of electrons in a covalent bond to give both atoms a full outer shell
How do the Melting and Boiling Points Change going Down Group 7? Increase (Fluorine lowest → Iodine highest)
What Colour and State are the Following at Room Temperature? > Fluorine > Chlorine > Bromine > Iodine > Fluorine - Yellow Gas > Chlorine - Green Gas > Bromine - Orange Liquid > Iodine - Grey Solid
What is the Chemical Test for Chlorine? Damp blue litmus paper turns red then bleaches white
How and Why does Reactivity Change as you do Down Group 7? > Reactivity decreases > Electron is harder to attract > Outer shell is further from the nucleus > Electrostatic shielding from shells > Less attraction to the nucleus > Less energy available to attract electron
What is the General Word Equation for Reactions with Metals and Halogens? Halogen + Metal → Metal Halide (Salt)
What is the General Word Equation for Reactions with Hydrogen and Halogens? Halogen + Hydrogen → Hydrogen Halide
What happens when Hydrogen Halides Dissolve in Water? Form acidic solutions (e.g. HCl forms Hydrochloric Acid)
What happens if a More Reactive Halogen Reacts with a Halogen Compound? More reactive halogen displaces the less reactive one
Why are Halogen Displacement Reactions Redox? > Halogen Gains Electrons (Reduction) > Halide Ions Loose Electrons (Oxidation)
What are Group 0 Elements also known as? Noble Gases
How many Outer Electrons do Group 0 Metals have? Full Outer Shell (2, 8, 8 for first 3 periods)
What are the Physical and Chemical Properties of Group 0 Elements? > Colourless Gases (at room temp.) > Monatomic (exist as single atoms) > Extremely unreactive (almost inert) > Non-Flammable > Low Melting / Boiling Points > Low Densities
Why are Group 0 Elements Inert? They have a full outer shell of electrons so they don't gain / loose / share electrons easily
What are some Uses of Noble Gases? > (All) Provide an Inert Atmosphere > Argon used in Filament Lamps (non-flammable) > Argon and Helium Protect Metals during Welding > Helium used in Airships and Party Balloons (Low-Density)
What happens to Melting / Boiling Points / Density as you go Down Group 0? > Melting / Boiling Points Increase > Density Increases
What is the Rate of Reaction? How Fast a Reaction Happens
How do Reactions Occur? Particles collide with enough energy to react
What is the Minimum Amount of Energy for a Reaction to Occur Called? The Activation Energy
How do you Increase the Rate of Reaction (generally)? Increase the Frequency of Collisions or Increase the Energy of Collisions (so they're more successful)
How do you Calculate the Rate of Reaction? Rate = Amount of Product Formed ÷ Time or Rate = Amount of Reactant Used ÷ Time
How do you Increase Rate of Reaction by Changing the Surface Area and why? > Increasing the surface area to volume ratio > Usually done by decreasing size of pieces (powdering them etc.) but overall volume is the same > There is more surface for collisions to occur > Collisions occur more frequently - faster rate of reaction
How do you Increase Rate of Reaction by Changing the Concentration and why? > Increasing the concentration > There are more reacting particles in the same volume > Collisions occur more frequently - faster rate of reaction
How do you Increase Rate of Reaction by Changing the Temperature and why? > Increasing the temperature > Reactant particles have more energy > More kinetic energy means particles move faster > Particles moving faster collide more frequently - faster rate of reaction > Particles with more energy successfully react more frequently - faster rate of reaction
How do you Increase Rate of Reaction by Changing the Pressure and why? > Increase the pressure > Same number of particles in a lower volume > Collisions occur more frequently - faster rate of reaction
How could you Test Rates of Reaction? > Measure how quickly a precipitate forms (if applicable) > Measure a change in mass (usually by gas being given off) > Measure a volume of gas given off
How would you Test Rates of Reaction by using a Precipitate being Formed? > Put a piece of paper with an X below the flask > Mix the two solutions > Time how long it takes for the X to "disappear" > Result is Subjective
How would you Test Rates of Reaction by using the Change in Mass? > Place the flask on scales > Mix the two solutions > Bung the flask with cotton wool (for safety) > Measure how quickly the mass decreases
How would you Test Rates of Reaction by using the Volume of Gas? > Mix the two solutions > Bung the flask with either a gas syringe or upside-down measuring cylinder filled with water > Measure the volume against the time elapsed > Faster the volume increases, the faster the reaction
When plotting Rates of Reaction on a Graph, how do you determine the Rate? The gradient
How do you calculate Gradient? Curved line: Draw a tangent off a specific point then Straight line: Gradient = Δy ÷ Δx (Δ = change in)
What do Catalysts do? Increase the Rate of Reaction without being Chemically Changed or Used Up
How do Catalysts Work? Decrease the Activation Energy needed for a Reaction to Occur by providing an Alternative Reaction Pathway
What are Enzymes and Where are they Found? Biological Catalysts found in Living Cells / Organisms
What is an Exothermic Reaction? A reaction which gives out energy to the surroundings - rise in temperature of the surroundings
What is an Endothermic Reaction? A reaction which takes in energy from the surroundings - fall in temperature of the surroundings
What is a Reaction Profile? A Graph which shows the Energy Levels of Reactants and Products in a Reaction
How do you tell if a Reaction is Exothermic on a Reaction Profile > Products have a Lower Energy than the Reactants > Difference in Height Represents the Energy Given Out
How do you tell if a Reaction is Endothermic on a Reaction Profile > Products have a Higher Energy than the Reactants > Difference in Height Represents the Energy Taken In
On a Reaction Profile, what is the Activation Energy? Energy Difference between the Reactants and the Peak of the Curve
Which of the Following Reactions are Exothermic, Endothermic or Both (depending on the elements): > Dissolving Salts > Neutralisation > Displacement > Precipitation > Dissolving Salts - Both > Neutralisation - Both (usually Exo) > Displacement - Exothermic > Precipitation - Exothermic
Is Breaking Chemical Bonds Endothermic or Exothermic Endothermic; it requires energy
Is Forming Chemical Bonds Endothermic or Exothermic Exothermic; it releases energy
How do you Calculate Overall Energy Change? Overall Energy Change = Energy Required to Break Bonds - Energy Released by Forming Bonds (Example in Revision Guide)
What is a Hydrocarbon? A molecule that contains Carbon and Hydrogen ONLY
What is a Homologous Series? A family of molecules which have the same general formula and share chemical properties
What is the General Formula for Alkanes? CₙH₂ₙ₊₂
What are the first 6 Alkanes and their Formulæ? Methane - CH₄ Ethane - C₂H₆ Propane - C₃H₈ Butane - C₄H₁₀ Methylbutane* - C₅H₁₂ Cyclohexane - C₆H₁₂ *aka pentane
Why are the Physical Properties Different in Alkanes / Hydrocarbons? The intermolecular forces are stronger between bigger molecules, which hold the chains of atoms together
Why do Longer Hydrocarbons have Higher Boiling Points? > Intermolecular forces break easier in SMALLER molecules > There is still another place where the force is strong enough to hold in in place > Bonds are harder to break so boiling point is higher
Why are Shorter Hydrocarbons Easier to Ignite? > Shorter hydrocarbons have lower boiling points > The gas molecules mix with oxygen in the air to produce a combustible gas mixture > If the mixture comes in contact with a spark, it will ignite
Why are Longer Hydrocarbons more Viscous? > Viscosity is how easily a substance flows > Stronger force between hydrocarbon molecules > Harder for the liquid to flow - higher viscosity
What does it mean if a Molecule is Saturated? All the atoms have formed bonds with as many other atoms as they can
What's the Difference between Alkanes and Alkenes? Alkanes - Saturated, they have all single bonds Alkenes - Unsaturated, they have a double bond
What is Cracking? Chemical reaction in which large alkane molecules are split into smaller alkanes and alkenes
What are the First Three Alkenes and their Formulæ? Ethene - C₂H₄ Propene - C₃H₆ Butene - C₄H₈
What is the Test for Alkenes? > Add orange bromine water > If the colour remains, it is an alkane > If the solution becomes colourless, it is an alkene
How does the Test for Alkenes with Bromine Water Work? > When an alkene reacts with bromine, the double bond breaks > At the same time, the atoms in the bromine molecule break apart > The bromine atoms are "added" to the broken ethene molecule (an addition reaction)
What do Hydrocarbons (alkanes and alkenes) form in Full Combustion Reactions? Carbon Dioxide (CO₂) and Water (H₂O)
Why must Tests for Ions be Unique? So only one ion can be identified
What Colour do the Following Ions Produce under a Flame? Lithium (Li⁺) Sodium (Na⁺) Potassium (K⁺) Calcium (Ca²⁺) Copper (Cu²⁺) Lithium (Li⁺) - (Crimson) Red Sodium (Na⁺) - Yellow Potassium (K⁺) - Lilac Calcium (Ca²⁺) - Orange-Red Copper (Cu²⁺) - Blue-Green
What Colour do the Following Ions Produce when Reacted with Sodium Hydroxide (NaOH)? Aluminium (Al³⁺) Calcium (Ca²⁺) Copper(II) (Cu²⁺) Iron(II) (Fe²⁺) Iron(III) (Fe³⁺) Magnesium (Mg²⁺) Aluminium (Al³⁺) - White Calcium (Ca²⁺) - White Copper(II) (Cu²⁺) - Blue Iron(II) (Fe²⁺) - Green Iron(III) (Fe³⁺) - Brown Magnesium (Mg²⁺) - White
How do you Test for Ammonium Ions (NH₄⁺) with Sodium Hydroxide (NaOH)? Reaction of NH₄⁺ and NaOH produce ammonia gas, which turns a moistened, red litmus paper blue
What is Flame Photometry? An instrumental method which allows you to identify flame colours from ions
How can you measure the Concentration of an Ion using Flame Photometry? The intensity of a measured wavelength indicates the concentration of that ion
What are the Advantages of Flame Photometry? > Very sensitive - can detect small amounts of substances > Very fast - tests can be automated > Very accurate - tests eliminate human error > Works for mixtures - the accuracy allows for multiple ions to be detected and cross-referenced
What Colour Precipitate do the Following Ions Produce when Reacted with Silver Nitrate (AgNO₃)? Chloride (Cl⁻) Bromide (Br⁻) Iodide (I⁻) Chloride (Cl⁻) - White Bromide (Br⁻) - Cream Iodide (I⁻) - Yellow
What is the Test for Carbonate Ions (CO₃²⁻)? > Add dilute hydrochloric acid > Bubble any gas produced through limewater > If limewater turns cloudy, CO₃²⁻ ions are present (since there is CO₂ gas)
What is the Test for Sulfate Ions (SO₄²⁻)? > Add dilute hydrochloric acid > Add barium chloride solution > White precipitate will form is SO₄²⁻ is present
What are Nanoparticles? Tiny particles consisting of only a few hundred atoms
What is the Size of Nanoparticles 1 - 100 nanometres 1 nanometre = 1 × 10⁻⁹m ... like m'dick- what
What Properties of Nanoparticles make them Useful? > Small Size > Large Surface Area : Volume Ratio
What are some Examples of the Uses of Nanoparticles? > Titanium Dioxide - absorbs UV radiation and is also near-invisible > SA:V ratio make them good Catalysts - stain-resistant clothes are often treated with nanoparticulate to catalyse dirt > Nanomedicine - tiny fullerenes are absorbed more easily into the body > Lubricants > Tiny electrical circuits - such as ones in computers' chips and more
What are some Risks of Using Nanoparticles? > Small size may pose hazards to human health > They can be breathed in or pass through cell membranes easily > The SA:V ratios could make them catalyse harmful reactions > They could easily carry toxic substances bound to them
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