Chem 4 - Organic Synthesis

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Chem 4 - Organic Synthesis
katy stopforth
Flashcards by katy stopforth, updated more than 1 year ago
katy stopforth
Created by katy stopforth about 8 years ago
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Question Answer
Alkane 》Haloalkane Free Radical Substitution Cl₂ UV Light
Alkene 》Haloalkane Electrophilic Addition of HBr HBr Room Temperature
Alkene 》Dibromoalkane Electrophilic Addition of Bromine Br₂ Room Temperature
Alkene 》Alcohol Direct Hydration of Alkenes H₃PO₄ Catalyst Steam High Pressure
Alkene 》Alkane Hydrogenation Hydrogen Nickel Catalyst 150⁰c
Alkene 》Polymer Polymerisation of Alkenes
Haloalkane 》Alcohol Nucleophilic Substitution warm NaOH (aq) reflux
Haloalkane 》Amine Nucleophilic Substitution aqueous alcoholic ammonia (in excess) reflux under pressure
Haloalkane 》Nitrile Nucleophilic Substitution aqueous alcoholic KCN reflux
Nitrile 》Carboxylic Acid Reduction C₂H₅CN + 2H₂O → C₂H₅COOH + NH₃
Nitrile 》Amine Hydrolysis C₂H₅CN + 4[H] → C₂H₅CH₂NH₂ LiAlH₄ dilute H₂SO₄
Haloalkane 》Alkene Elimination alcoholic NaOH reflux
Alcohol 》Alkene Elimination of Water (Dehydrogenation) concentrated H₂SO₄ reflux at 180⁰c
Alcohol (1⁰) 》Aldehyde Oxidation of Primary Alcohols acidified K₂Cr₂O₇ H₂SO₄ heat in distillation apparatus
Aldehyde 》Carboxylic Acid Oxidation of Aldehydes acidified K₂Cr₂O₇ H₂SO₄ reflux
Alcohol (2⁰) 》Ketone Oxidation of Secondary Alcohols acidified K₂Cr₂O₇ H₂SO₄ heat in distillation apparatus
Carboxylic Acid 》Aldehyde Reduction of Carboxylic Acids LiAlH₄ reflux in ethoxyethane
Aldehyde 》Alcohol (1⁰) Reduction of Aldehydes NaBH₄ water methanol
Ketone 》Alcohol (2⁰) Reduction of Ketones NaBH₄ water methanol
Alcohol 》Ester Esterification carboxylic acid concentrated H₂SO₄ catalyst reflux
Carboxylic Acid 》Ester Esterification alcohol concentrated H₂SO₄ catalyst reflux
Ester 》Alcohol Hydrolysis of Esters dilute H₂SO₄ catalyst H₂O reflux or dilute NaOH (aq) reflux
Ester 》Carboxylic Acid Hydrolysis of Esters dilute H₂SO₄ catalyst H₂O reflux or dilute NaOH (aq) reflux
Alcohol 》Haloalkane Bromination of Alcohols potassium bromide concentrated H₂SO₄ reflux
Benzene 》Phenylketone Acylation aycl chloride AlCl₃ catalyst reflux non-aqueous environment
Benzene 》Nitrobenzene Nitration concentrated H₂SO₄ concentrated HNO₃ below 55⁰c
Nitrobenzene 》Aromatic Amine Reduction Sn concentrated HCl then NaOH(aq) reflux
Aromatic Amine 》N-phenylethanamine Addition-Elimination CH₃COCl
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