Organic Chemistry (Aliphatic)

Beschreibung

Chemistry (Organic Chem) Mindmap am Organic Chemistry (Aliphatic), erstellt von Cindy Lam am 04/04/2013.
Cindy Lam
Mindmap von Cindy Lam, aktualisiert more than 1 year ago
Cindy Lam
Erstellt von Cindy Lam vor etwa 11 Jahre
456
0

Zusammenfassung der Ressource

Organic Chemistry (Aliphatic)
  1. Carboxylic Acid (RCOOH)
    1. Formation
      1. Oxidation of Aldehydes
        1. Hydrolysis of Esters, AC, nitriles, amides
        2. P.Prop
          1. H-bond → soluble in organic solvents and water
          2. RCOOH + PCL5 → RCOCl + POCl3 + HCl
            1. Formation of Acyl Chloride (RCOCl)
          3. Esters (R'COOR)
            1. Formation
              1. C.A + A: Reflux, Strong acid
                1. AC/AA + A: Reflux, Dry
                  1. AA less reactive → slower, less toxic, less exothermic
                2. C.Prop
                  1. Relatively unreactive
                  2. Hydrolysis break O bridge
                    1. Acidic: Reversible
                      1. Basic: 1D, Water soluble ionic salt formed, then react with HCl
                      2. Uses
                        1. Nice smell
                          1. Solvent
                            1. Plasticisers
                              1. Saponification - Alkaline Hydrolysis of triglycerol esters
                                1. Biodiesel
                              2. Amides (RCONH2)
                                1. Hydrolysis
                                  1. +H2O → RCOOH + NH3
                                    1. +HCl → RCOOH + NH4Cl
                                      1. +NaOH → RCOONa + NH3
                                      2. Reduce to primary amines
                                      3. Nitriles (RCN)
                                        1. Aldehydes (RCHO)
                                          1. Formation
                                            1. Oxi of primary Alcohols
                                              1. Reduction of CA
                                              2. Easily oxidised
                                              3. Ketones (R'COR)
                                                1. Oxi of secondary alcohols
                                                  1. Resistant to oxidation
                                                  2. Acyl Chlorides (RCOCl)
                                                    1. +Amines → N-substituted amides
                                                      1. +Ammonia → Amide
                                                        1. → Esters
                                                        2. Alcohol (ROH)
                                                          1. Identification Tests

                                                            Anlagen:

                                                            Zusammenfassung anzeigen Zusammenfassung ausblenden

                                                            ähnlicher Inhalt

                                                            Acids and Bases
                                                            Sarah Egan
                                                            Using GoConqr to study science
                                                            Sarah Egan
                                                            Ionic Bondic Flashcards.
                                                            anjumn10
                                                            Electrolysis
                                                            lisawinkler10
                                                            Acids and Bases
                                                            silviaod119
                                                            Elements, Compounds and Mixtures
                                                            silviaod119
                                                            Chemistry General Quiz - 2
                                                            lauren_johncock
                                                            Chemistry Quiz General -3
                                                            lauren_johncock
                                                            Chemistry Module C2: Material Choices
                                                            James McConnell
                                                            AS Chemistry - Enthalpy Changes
                                                            Sarah H-V
                                                            The Periodic Table
                                                            asramanathan