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Biofuels Final

Shea Poage Inglés 36 fichas

Fichas del conjunto (36)

  1. 1Bulk DensityAspect of biomass characterization that determines how far a feedstock can economically travel
  2. 2Ideal carbon:nitrogen ratio30:1
  3. 3Ethanol was manufactured to replace what carcinogenic fuel additive?MTBE
  4. 4Life cycle analysisLooks at all aspects of biofuel production
  5. 5Methane has how many times the global warming potential of CO2?21
  6. 6StarchPolymer of glucose molecules, most abundant form of food reserves in plants
  7. 7PyrolysisThermal decomposition of carbon based materials in the absence of oxygen
  8. 8Carbon neutralMeans the fuel produced is offsetting the amount of carbon it releases somehow. Net carbon emissions are zero. Carbon sequestration.
  9. 94 strokes in the otto cycle internal combustion engineIntake-fuel is injected into cylinder
    Compression-fuel is compressed
    Combustion-fuel is sparked/ignited
    Exhaust-products of combustion are released to make room for more fuel
  10. 10Chemical reaction for complete combustion of methaneCH4 + 2O2 ----> CO2 + 2H2O
  11. 114 steps in combustionDrying, pyrolysis, gas combustion, solid combustion
  12. 12Ratios of principle components of biogas/landfill gas & how to refine50% methane, 50% CO2, trace amounts of H2S. To get rid of CO2, bubble through solution of lime. To get rid of H2S, iron filings or steel wool
  13. 13Second generation biofuelsFeedstocks that aren't food crops. Includes nonfood crops (switchgrass) and waste streams (animal manure, MSW). Major obstacles to implementation include lack of available farm land and infrastructure
  14. 14Know how to sketch a simple anaerobic digester!Duh
  15. 15Know how to sketch a simple batch biochar makerDuh
  16. 16Motivation for biofuels on a global perspectiveUS-decrease foreign oil dependency
    Europe-environment
    lesser income countries-economic development
  17. 17Indirect land use changeCrop starts being sued for fuel, increases in value. Price increases affect consumers. More people want to grow it, so more farmland gets used for it. Food vs fuel.
  18. 1810% in 10 year biofuel production goal: What are some strategies?Marginal land for switchgrass,
    Pig manure as feedstock for black soldier fly larvae
  19. 19Food vs fuel debateWon't have enough crops to feed everyone
    (but US grows so much, that's really not an issue)
    Food prices will go up
  20. 20Biodiesel recipe1. Collect, process, and heat oil.
    2. Measure 1 part methanol to 5 parts oil.
    3. Measure lye (NaOH or KOH), 9 g per liter, and mix methoxide (catalyst).
    4. Mix oil and methoxide together for 1 hour.
    5. Settle, then drain glycerin.
  21. 21ASTMAmerican Society for Testing and Materials
  22. 22Examples of ASTM quality testsFlash point, water & sediment, kinematic viscosity, sulfated ash, sulfur, copper strip corrosion, cetane number, cloud point, carbon residue, acid number, free glycerin, total glycerin, phosphorus content, distillation temperature
  23. 233/27 testAdd 3mL biodiesel to 27mL methanol (1:9 ratio). Should dissolve completely, if not, incomplete reaction likely
  24. 24Water testAdd 50% water. Note separation, clarity, clouding. Indicates residual materials
  25. 25PHLIP testQualitative test with color chart to indicate residual soaps, glycerin, water, and other contaminants
  26. 26Total glycerinLevels >0.24% indicates incomplete reaction. If fuel fails this spec, nothing else matters.
  27. 27Safety concerns in biodiesel processing: potential hazardsFire, chemical exposure, spills, explosion
  28. 28Safety concerns in biodiesel processing: PPEGloves, goggles, ventilation, acid for neutralization (vinegar)
  29. 29Safety concerns in biodiesel processing: additional safety measuresFire extinguisher, secondary containment, sealed vessels, respirators, explosion proof motors, pumps rated for volatile materials, grounding
  30. 30Energy balance (AKA Energy Return on Energy Invested, EROEI)An indication of the energy efficiency of a process, expressed as a ration (fuel product energy: input energy).
  31. 31LCA factors of biodieselAgriculture (work on fields, seeds, fertilizers, pesticides, harvest, emissions from fields), conversion (transport, storage, transport to mill, recovery & refining of oil, tranesterification), use (final transport & combustion).
  32. 32SaponificationProcess of making glycerol & soap.
    Fat + sodium hydroxide ----> glycerol + crude soap
  33. 33Ethanol history and developmentModel A ran ethanol. Rockefeller funded prohibition to have gasoline as the only fuel. Otto invented 4-stroke engine in 1872, engines ran on alcohol b/c there was no gasoline. FlexFuel & E85 (USA). It's everywhere in Brazil!
  34. 34Primary feedstocks by countryBrazil-sugarcane
    USA-corn
  35. 35Energy densityEthanol's energy density is lower than gasoline. 1 gal ethanol=75,500 Btus, 1 gal gasoline=110,000 Btus. However, increased octane of ethanol improves combustion efficiency
  36. 36Production stepsMashing, fermentation, distillation

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Fichas sobre Biofuels Final, creado por Shea Poage el 10/12/2015.
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Shea Poage
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