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Why is benzene less reactive than alkenes?

Fauzia Ali Chemistry A-Level Inglés 3 fichas

Why is benzene less reactive than alkenes?

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  1. 1Why is benzene less reactive than alkenes?Why is benzene less reactive than alkenes?
  2. 2In cyclohexene the pi bond is made by sideways overlap of p orbitals on adjacent carbon atoms. Whereas for benzene, the pi bond is made by the sideways overlap of p orbitals on all 6 carbons atoms adjacent to each otherTherefore on benzene the 6 pi electrons are delocalised over 6 carbon atoms
    On cyclohexane the two pi electrons are localised between the two carbon atoms
  3. 3Therefore cyclohexene has a higher pi electron density than benzene and will attract electrophiles more strongly as it induces a bigger dipoleSo alkenes are more reactive than benzene

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A-Level (Module 6) Chemistry Fichas sobre Why is benzene less reactive than alkenes?, creado por Fauzia Ali el 08/02/2017.
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Fauzia Ali
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