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F322 chains, energy and resources

kira.kyne chemistry Inglés 29 fichas

F322 chains, energy and resources

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  1. 1interpret and use the terms: (i) empirical formulaas the simplest whole
    number ratio of atoms of each element
    present in a compound
  2. 2interpret and use the terms: (ii) molecular formulaas the actual number of
    atoms of each element in a molecule,
  3. 3interpret and use the terms: (iii) general formulaas the simplest algebraic
    formula of a member of a homologous
    series, ie for an alkane: CnH2n + 2
  4. 4interpret and use the terms: (iv) structural formulaas the minimal detail that
    shows the arrangement of atoms in a
    molecule,
    eg for butane: CH3CH2CH2CH3 or
    CH3(CH2)2CH3
  5. 5intepret and use the terms: (v) displayed formulaas the relative
    positioning of atoms and the bonds
    between them, ie for ethanol
  6. 6interpret and use the terms: (vi) skeletal formulaas the simplified organic
    formula, shown by removing hydrogen
    atoms from alkyl chains, leaving just a
    carbon skeleton and associated functional
    groups, ie for butan-2-ol
  7. 7interpret, and use, the terms: (i) homologous seriesas a series of organic
    compounds having the same functional
    group but with each successive member
    differing by CH2
  8. 8interpret, and use, the terms: (ii) functional groupas a group of atoms
    responsible for the characteristic reactions
    of a compound
  9. 9use the general formula of a homologous series to predict the formula of any member of the seriesdiffer by CH2
  10. 10state the names of the first ten members of the alkanes homologous seriesmethane,ethane,propane,butane, pentane, hexane, heptane, octane, nonane, decane
  11. 11use IUPAC rules of nomenclature for systematically naming organic compoundssystematic naming, ie
    2-methylbutan-1-ol
  12. 12describe and explain the terms: (i) structural isomerscompounds with the
    same molecular formula but different
    structural formulae
  13. 13describe and explain the terms: (ii) stereoisomersas compounds with the
    same structural formula but with a different
    arrangement in space
  14. 14describe and explain the terms: (iii) E/Z isomerismas an example of
    stereoisomerism, in terms of restricted
    rotation about a double bond and the
    requirement for two different groups to be
    attached to each carbon atom of the C=C
    group
  15. 15describe and explain in terms: (iv) cis-trans isomerismas a special case of
    EIZ isomerism in which two of the
    substituent groups are the same
  16. 16determine the possible structural formulae and/or stereoisomers of an organic molecule, given its molecular formula....
  17. 17describe the different types of covalent bond fission(i) homolytic fission forming two radicals, Cl--Cl---->cl. + cl. breaks evenly
    (ii) heterolytic fission forming a cation and an anion Cl--Cl ---> Cl+ + Cl-
  18. 18describe a ‘curly arrow’as the movement of an electron pair, showing either breaking or formation of a covalent bond
  19. 19outline reaction mechanisms, using diagrams, to show clearly the movement of an electron pair with ‘curly arrows’use curly arrows during electrophilic addition and nucleophilic substitution.
  20. 20carry out calculations to determine the percentage yield of a reaction% yield =(actual yield/predicted yield)X100
  21. 21explain the atom economy of a reaction as:molecular mass of the desired products /sum of molecular masses of all products X100%;
  22. 22explain that addition reactions have an atom economy of 100%, whereas substitution reactions are less efficientaddition makes 1 product while substitution has 1 desired product and 1 waste product
  23. 23describe the benefits of developing chemical processes with a high atom economy in terms of fewer waste materials;fewer waste materials, so more product from reactants, more economically viable
  24. 24explain that a reaction may have a high percentage yield but a low atom economyreactions can produce a high amount of products but they may predominantly be the undesired products so atom economy will be low. must find a compromise between both.
  25. 25Candidates should be able to: explain that a hydrocarbon is:a compound of hydrogen and carbon only
  26. 26Candidates should be able to: explain the use of crude oil asa source of hydrocarbons, separated as fractions with different boiling points by fractional distillation, which can be used as fuels or for processing into petrochemicals.
  27. 27Candidates should be able to: state that alkanes and cycloalkanes are...saturated hydrocarbons
  28. 28Candidates should be able to: state and explain the tetrahedral shape around each carbon atom in alkanesCandidates should be able to: state and explain the tetrahedral shape around each carbon atom in alkanes
  29. 29explain, in terms of van der Waals’ forces, the variations in the boiling points of alkanes with different carbon-chain length and branchingmore branches, less van der waals' and lower BP
    longer chain, more van der Waals', higher BP

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chemistry Fichas sobre F322 chains, energy and resources, creado por kira.kyne el 19/04/2014.
Creado por
kira.kyne
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Etiquetas
chemistry
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