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25.4- DIRECTING GROUPS

vittoria howard A2 CHEMISTRY A2 Inglés 15 fichas

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  1. 1What 2 isomers are formed when phenol undergoes an electrophilic substitution reaction with nitric acid?2-nitrophenol and 4-nitropheol.
  2. 2What is a second substitution called?Disubstitution.
  3. 3Does bromine require a halogen carrier catalyst to react with benzene?Yes.
  4. 4Does bromine require a halogen carrier catalyst to react with phenylamine?No.
  5. 5How fast does nitrobenzene react with bromine and what conditions are required?Nitrobenzene reacts slowly with bromine. It requires a halogen carrier catalyst and a high temperature.
  6. 6Is the benzene ring in nitrobenzene more or less susceptible to electrophilic substitution than benzene itself?Less.
  7. 7Where does the -NH2 group direct the second substituent?Positions 2 or 4.
  8. 8Where does the -NO2 group direct the second substituent?Position 3.
  9. 9What position does ortho refer to?2.
  10. 10What position does meta refer to?3.
  11. 11What position does para refer to?4.
  12. 12Which directing groups are activating?2 and 4 (ortho and para).
  13. 13Which directing groups are deactivating?3 (meta).
  14. 14What are 8 examples of 2- and 4-directing groups? (activating)-NH2, -OH, -OR, -C6H5, -F, -Cl, -Br, -I
  15. 15What are 8 examples of 3- directing groups? (deactivating)RCOR, -COOR, -SO3H, -CHO, -COOH, -CN, -NO2, -NR3+.

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A2 (AROMATIC COMPOUNDS) A2 CHEMISTRY Fichas sobre 25.4- DIRECTING GROUPS, creado por vittoria howard el 21/11/2016.
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