Flashcards
Chapter 2 - FGI with Amine Synthesis
Flashcards do conjunto (19)
- 1—
- 2—SOCl_2
- 3—
- 4—i) LiAlH_4
ii) Dilute HCl (work-up)
- 5—
- 6—
- 7—
- 8Via Imines
- 9—
- 10Via Azides
- 11—1) DMSO
2) LiAlH_4
- 12—
- 13—
- 14—1) LDA
2) LiAlH_4, Dilute HCl work-up
- 15Reason for using biphasic conditionsto avoid reaction between OH- and electrophile
- 16Example of a biphasic solventNaOH
- 17What is a 'phase transfer' catalyst?base that is soluble in the organic phase that is used in a biphasic reaction mixture
- 18Example of a 'phase transfer' catalystBnEt_3NCl
- 19—1) azide, pthalimide, oxime
2) cyanide, nitromethane
3) acetonitrile