AQA Chemistry C4: Chapter 5: Compounds Containing the Carbonyl Group

Descrição

AQA A2
stevbarretto
Quiz por stevbarretto, atualizado more than 1 year ago
stevbarretto
Criado por stevbarretto mais de 10 anos atrás
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Resumo de Recurso

Questão 1

Questão
Aldehydes and Ketones contain which functional group?
Responda
  • -OH
  • Benzene ring
  • C=O

Questão 2

Questão
Of these compounds with comparable relative molecular mass, which has the higher boiling point?
Responda
  • Alcohols
  • Alkanes
  • Carbonyl compounds

Questão 3

Questão
Tick which answers are true
Responda
  • Shorter chain aldehydes and ketones mix completely with water
  • Carbonyl compounds become more soluble as chain length increases
  • Carbonyl compounds become less soluble as chain length increases
  • Methanal is gas at room temperature
  • Methanal is liquid at room temperature
  • Short chain aldehydes and ketones are pleasant smelling liquids
  • Short chain aldehydes and ketones are pleasant smelling gases

Questão 4

Questão
Which reactions commonly occur with carbonyl compounds?
Responda
  • Electrophilic addition
  • Nucleophilic substitution
  • Nucleophilic addition
  • Redox
  • Neutralisation

Questão 5

Questão
Reactions of Aldehydes and Ketones with Hydrogen Cyanide (:CN-) produce what?
Responda
  • Carboxylic acids
  • Amines
  • Amides
  • N-Substituted Amides
  • Hydroxynitriles
  • Esters
  • Alcohols

Questão 6

Questão
A nucleophilic reaction produces a racemic mixture when a nucleophile attacks which of these?
Responda
  • A symmetrical Ketone
  • An Aldehyde
  • An unsymmetrical Ketone

Questão 7

Questão
What does acidified potassium dichromate do to aldehydes?
Responda
  • Oxidise to ester
  • Reduce to ester
  • Oxidise to alcohol
  • Reduce to alcohol
  • Oxidise to carboxylic acid
  • Reduce to carboxylic acid
  • Nothing

Questão 8

Questão
What does acidified potassium dichromate do to ketones?
Responda
  • Oxidise to ester
  • Reduce to ester
  • Oxidise to carboxylic acid
  • Reduce to carboxylic acid
  • Oxidise to alcohol
  • Reduce to alcohol
  • Nothing

Questão 9

Questão
Colour of Fehlings solution?
Responda
  • Green
  • Orange
  • Red
  • Brown
  • Pink
  • Blue

Questão 10

Questão
When an aldehyde is warmed with Fehlings solution a precipitate is formed. What colour?
Responda
  • Red
  • Green
  • Blue
  • Orange
  • Yellow
  • Pink
  • Black

Questão 11

Questão
When an aldehyde is warmed with Tollens reagent __________ is formed
Responda
  • Metallic silver
  • Red precipitate
  • Blue precipitate

Questão 12

Questão
Reducing agents (e.g. NaBH4) can reduce aldehydes and ketones to ____________
Responda
  • Carboxylic acids
  • Esters
  • Alcohols
  • Alkanes
  • Alkenes

Questão 13

Questão
Reducing agent sodium tetrahydridoborate(III) generates which nucleophile?
Responda
  • -F
  • -OH
  • -H
  • -CH3
  • -NH2

Questão 14

Questão
Benzene ring with carboxylic acid group attached is called..?
Responda
  • Phenylcarboxylic acid
  • Carboxylbenzoic acid
  • Benzenecarboxylic acid

Questão 15

Questão
Carboxylic acids are completely soluble in water. (Up to C4 only)
Responda
  • True
  • False

Questão 16

Questão
Carboxylic acids have lower melting points than alkanes of similar relative molecular mass
Responda
  • True
  • False

Questão 17

Questão
Thiele tube measures ______________ of carboxylic acids
Responda
  • Colour
  • Boiling point
  • Viscocity
  • Electronegativity
  • Amounts
  • Melting Points

Questão 18

Questão
Glacial ethanoic acid is...?
Responda
  • Cooler
  • Pure ethanoic acid
  • Ethanoic acid from glaciers

Questão 19

Questão
How to name esters?
Responda
  • Group attached to oxygen comes first followed by R-COO
  • R-COO comes first and the group attached to oxygen comes last

Questão 20

Questão
Which has pleasant fruity smells?
Responda
  • Long chain esters
  • Short chain esters

Questão 21

Questão
The H in R-COOH (carbox. acid) can be lost as H+ leaving [R-COO]- what is this ion called
Responda
  • Carboxyl ion
  • Carboxylate ion
  • Carboxilic ion
  • Carboxylic acid ion

Questão 22

Questão
How to distinguish between carboxylic acids and other organic compounds?
Responda
  • React with water
  • React with sodium hydrogencarbonate
  • React with potassium dichromate

Questão 23

Questão
Ionic salts formed from carboxylic acids donating protons are called? (e.g. Ethanoic Acid + Sodium Hydroxide -> *Sodium Ethanoate* + Water)
Responda
  • Carboxyls
  • Carboxylates
  • Carboxylic salts
  • Carboxyl salt

Questão 24

Questão
Esters are formed in which reaction?
Responda
  • Alcohol + Ketone
  • Alcohol + Aldehyde
  • Aldehyde + Ketone
  • Alcohol + Carboxylic Acid
  • Carboxylic Acid + Aldehyde
  • Carboxylic Acid + Ketone
  • Carboxylic Acid + Alkene

Questão 25

Questão
This reaction (sped up by a strong acid catalyst) forms............?
Responda
  • Non equilibrium mixture
  • An equilibrium mixture

Questão 26

Questão
_____(1)______ is attacked by water acting as a _______(2)______ in the hydrolysis of esters
Responda
  • R group
  • R' group
  • Carbonyl Oxygen
  • Carbonyl Carbon
  • Strong nucleophile
  • Weak nucleophile
  • Weak electrophile
  • Strong base
  • Weak base
  • Weak acid

Questão 27

Questão
Equilibrium mixture of the hydrolysis of esters contains which of these..?
Responda
  • Alcohol
  • Ester
  • Base
  • Acid
  • Water
  • CO2

Questão 28

Questão
Fats and oils can be hydrolysed by boiling with NaOH to produce?
Responda
  • Water
  • CO2
  • Glycerol
  • Sodium Salts

Questão 29

Questão
Salts formed from hydrolysis of fats and oils using NaOH are used in?
Responda
  • Soaps
  • Paint
  • Sun cream

Questão 30

Questão
What group is this? (Picture)
Responda
  • Aryl
  • Methyl
  • Acyl
  • Carbonyl

Questão 31

Questão
Esters, Acid Chlorides and Acid Anhydrides are examples of?
Responda
  • Acyl derivatives
  • Acid derivatives

Questão 32

Questão
Acyl chlorides and acid anhydrides are bad acylating agents
Responda
  • True
  • False

Questão 33

Questão
Acid chlorides are more reactive than acid anhydrides
Responda
  • True
  • False

Questão 34

Questão
Acyl Chlorides and Acid Anhydrides react with the following nucleophiles but in which order of reactivity?
Responda
  • Primary Amine>Ammonia>Alcohol>Water
  • Water>Primary Amine>Alcohol>Ammonia
  • Ammonia>Primary Amine>Alcohol>Water

Questão 35

Questão
In these reactions between Acyl chlorides/Acid anhydrides and nucleophiles what type of reaction takes place?
Responda
  • Addition reaction
  • Elimination reaction
  • Electrophilic reaction
  • Neutralisation reaction
  • Addition-elimination reaction
  • Electrophilic-elimination reaction

Questão 36

Questão
In addition-elimination reactions: If the nucleophile is ammonia the product is an/a...?
Responda
  • N-substituted amide
  • Amide
  • Ester
  • Carboxylic Acid

Questão 37

Questão
In addition-elimination reactions: If the nucleophile is a primary amine the product is an/a...?
Responda
  • N-substiuted amide
  • Amide
  • Ester
  • Carboxylic Acid

Questão 38

Questão
In addition-elimination reactions: If the nucleophile is the -OH group of an alcohol the product is an/a...?
Responda
  • N-Substituted amide
  • Amide
  • Carboxylic acid
  • Ester

Questão 39

Questão
In addition-elimination reactions: If the nucleophile is water the product is an/a...?
Responda
  • N-substituted amide
  • Amide
  • Carboxylic Acid
  • Ester

Questão 40

Questão
Ethanoic anhydride as an acylating agent is cheaper than ethanoyl chloride.
Responda
  • True
  • False

Questão 41

Questão
Ethanoic anhydride as an acylating agent is more corrosive than ethanoyl chloride.
Responda
  • True
  • False

Questão 42

Questão
Ethanoic anhydride as an acylating agent reacts less readily with water than ethanoyl chloride.
Responda
  • True
  • False

Questão 43

Questão
Ethanoic anhydride as an acylating agent is safer than ethanoyl chloride due their by-products
Responda
  • True
  • False

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