ALKANES

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AS organic chemistry flashcards on alkanes
Monica Rodrigues
Flashcards by Monica Rodrigues, updated more than 1 year ago
Monica Rodrigues
Created by Monica Rodrigues over 7 years ago
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Question Answer
What is a hydrocarbon? A compound containing ONLY hydrogen and carbon atoms
What is a functional group? An atom or group of atoms that give a compound its characteristic chemical reactivity
What is a homologous series? A series of compounds that have the same FUNCTIONAL GROUP and the same GENERAL FORMULA. Successive members of the series differ by an extra CH2 unit
What is the meaning of saturated? An organic compound which contains ONLY single bonds between carbon atoms
What is the name given to the relationship between compounds with the same molecular formula? Structural isomers
When does incomplete combustion occur? When there is insufficient oxygen
Why is incomplete combustion a problem? Carbon monoxide binds to haemoglobin not allowing oxygen to do so. + CO is toxic and prolonged exposure is fatal.
Why the reaction of an halogen with an alkane not a particularly good way to manufacture a desired compound? - It's a radical substitution reaction - Further substitution may occur - Many other products are made - Yield of wanted product is low
What is a radical? An atom or group of atoms with an unpaired electron
What is homolytic fission? A process where a covalent bond breaks so that one electron making up the covalent bond stays with one atom and the other electron stays with the other
What are the stages of radical substitution? 1. INITIATION: UV breaks bonds in halogen forming radicals 2. PROPAGATION: Radical reacts with alkane (takes H from alkane) leaves alkane as a radical : Alkane radical takes an atom from halogen molecule 3. TERMINATION: any 2 radicals react -> stable molecule
What are the conditions required for radical substitution to occur? UV light
What are isoelectronic species? Elements or ions that have the same, or equal number of electrons
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