Flashcards
Organic Chemistry
Cards in this deck (7)
- 1Alcohol to AldehydePyridinium Chlorochromate
C5H5NH+CrO3Cl- - 2Cycloalkane to CycloketoneChromic Oxide
CrO3 - 3Fluorotoluene to Fluorobenzaldehyde1. Etard reaction (CrO2O3 ->Chromium complex-> Aldehyde)
2. CrO3 + acetic anhydride -> benzylidenen diacetate -> Aldehyde - 4Ethanenitrile to Ethanal1. Stephen reaction (SnCl2 + HCl -> Imine -> Aldehyde)
2. Reduction with DIBAL -H -> Hydrolysis - 5Allyl alcohol to PropenalPCC
- 6But-2-ene to EthanalOzonolysis / H2O - Zn dust
- 7Order of boiling pointsHydrocarbon < Ether < Aldehyde < Ketone < Alcohol
1. Hydrocarbon - van der Waal's forces
2. Aldehyde > Ether - More polar
3. Aldehyde, ketone < Alcohol - only weak dipole-dipole interactions as opposed to hydrogen bonding