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Benzene and aromatic compounds

Reuben Veysey-Smith Chemistry A-Level Inglés 10 fichas

Delocalised model

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  1. 1Kekules basic structureHe proposed that benzene was a flat ring of carbon atoms with alternating single and double bonds, he later adapted this to say the double and single bonds are constantly flipping
  2. 2Bond reason to reject kekules modelYou'd expect there to always be three c-c bond lengths of (154pm) and three C=C (134pm),but they all have a bond length of 140lm so it can't be right
  3. 3Delocalised modelThis states the p orbitals of all six carbon atoms overlap to make a system of two ring clouds above and below the BenzeneDelocalised model
  4. 4Hydrogenation disregarding kekules structureIf you hydrolyse an a Alkene you get an enthalpy change of -120. So the expected value would be -360 for hence but it is actually -208. This indicates benzene is more stable, and disregards kekules model
  5. 5Common prefixes for benzeneCl - chloro
    Br - bromo
    NO2 - nitro
    CH3 - methyl
  6. 6Benzene phenyl group namesOH - phenol
    NH2 - phenylamine
  7. 7Delocalised electrons in benzeneThe pi bonded electrons are delocalised, which spreads out the charge across the carbon atoms
  8. 8What is a delocalised electronOnes which are spread over more than 2 atoms
  9. 9Why is benzene so unreactiveThe electrons are spread out meaning a low charge density and thus means it does not attract electrophiles
  10. 10Properties of the benzene rings120 bond angles and the delocalised rings are planar

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A-Level (6.1) Chemistry Fichas sobre Benzene and aromatic compounds , creado por Reuben Veysey-Smith el 21/11/2016.
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