17782927
Description
Flashcards by John Rivada, updated more than 1 year ago
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Created by John Rivada
about 5 years ago
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| Question | Answer |
| Properties for kinetic product | -Forms faster -Rx usually short -Low temperature -Reversible under thermodynamic conditions |
| Properties for thermodynamic product | -Forms more slowly but more stable -Rx is long -High temperature -Irreversible |
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| How do you protect the amine group of an amino acid? | Cbz Benzyl chloroformate |
| How do you protect the amine group of an amino acid? | Boc (t-BuOCO) Deprotect with H+ and H2O |
| How do you protect the amine group of an amino acid? | FMoc-Cl, base Deprotect with amine base (e.g. pyridine) |
| How to make t-butyl ester | ** |
| How do you protect the carboxylic acid group of an amino acid? | ROH, H+ Deprotect with -OH (LiOH, NaOH) |
| How do you protect the carboxylic acid group of an amino acid? | isobutene, H+ Deprotect with strong acid |
| How do you protect the carboxylic acid group of an amino acid? | PHCH2OH and H+ or PhCH2Br and base Deprotect with H2 + cat. Pd/C or -OH |
| Slide 27 | ** |
| Slide 29 | ** |
| Slide 30 | ** |
| Solid phase peptide synthesis | 88 |
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